Iron(II) bromide

Iron(II) bromide
Names
IUPAC name
Iron(II) bromide
Other names
Ferrous bromide
Identifiers
CAS Number
  • 20049-61-0 tetrahydrate
  • 7789-46-0 anhydrous
3D model (JSmol)
  • Interactive image
ChemSpider
  • 74218 checkY
ECHA InfoCard 100.029.244 Edit this at Wikidata
PubChem CID
  • 425646
UNII
  • EA3X054RBZ checkY
CompTox Dashboard (EPA)
  • DTXSID201014482 DTXSID80976870, DTXSID201014482 Edit this at Wikidata
InChI
  • InChI=1S/2BrH.Fe/h2*1H;/q;;+2/p-2 checkY
    Key: GYCHYNMREWYSKH-UHFFFAOYSA-L checkY
  • InChI=1/2BrH.Fe/h2*1H;/q;;+2/p-2
    Key: GYCHYNMREWYSKH-NUQVWONBAN
  • [Fe+2].[Br-].[Br-]
Properties
Chemical formula
 FeBr2
Molar mass 215.65 g mol−1
Appearance yellow-brown solid
Density 4.63 g cm−3, solid
Melting point 684 °C (1,263 °F; 957 K) (anhydrous)
27 °C (Hexahydrate)
Boiling point 934 °C (1,713 °F; 1,207 K)
Solubility in water
 117 g / 100 ml
Solubility in other solvents THF, methanol, ethanol
Magnetic susceptibility (χ)
 +13,600·10−6 cm3/mol
Structure
Rhombohedral, hP3, SpaceGroup = P-3m1, No. 164
octahedral
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 none
Related compounds
Other anions
 Iron(II) fluoride
Iron(II) chloride
Iron(II) iodide
Other cations
 Manganese(II) bromide
Cobalt(II) bromide
Related compounds
 Vanadium(II) bromide
Iron(III) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound
Iron(II) bromide
Iron(II) bromide anhydrous

Iron(II) bromide refers to inorganic compounds with the chemical formula FeBr2(H2O)x. The anhydrous compound (x = 0) is a yellow or brownish-colored paramagnetic solid. The tetrahydrate is also known, all being pale colored solids. They are common precursor to other iron compounds.

Structure

Like most metal halides, FeBr2 adopts a polymeric structure consisting of isolated metal centers cross-linked with halides. It crystallizes with the CdI2 structure, featuring close-packed layers of bromide ions, between which are located Fe(II) ions in octahedral holes.[1] The packing of the halides is slightly different from that for FeCl2, which adopts the CdCl2 motif. The tetrahydrates FeX2(H2O)4 (X = Cl, Br) have similar structures, with octahedral metal centers and mutually trans halides.[2]

Synthesis and reactions

FeBr2 is synthesized using a methanol solution of concentrated hydrobromic acid and iron powder. It adds the methanol solvate [Fe(MeOH)6]Br2 together with hydrogen gas. Heating the methanol complex in a vacuum gives pure FeBr2.[3]

FeBr2 reacts with two equivalents of tetraethylammonium bromide to give [(C2H5)4N]2FeBr4.[4] FeBr2 reacts with bromide and bromine to form the intensely colored, mixed-valence species [FeBr3Br9]−.[5]

Magnetism

FeBr2 possesses a strong metamagnetism at 4.2 K and has long been studied as a prototypical metamagnetic compound.[6][7]

References

  1. ^ Haberecht, J.; Borrmann, Η.; Kniep, R. (2001). "Refinement of the crystal structure of iron dibromide, FeBr2". Zeitschrift für Kristallographie - New Crystal Structures. 216 (1–4). doi:10.1524/ncrs.2001.216.14.544.
  2. ^ Waizumi, Kenji; Masuda, Hideki; Ohtaki, Hitoshi (1992). "X-ray Structural Studies of FeBr2·4H2O, CoBr2·4H2O, NiCl2·4H2O and CuBr2·4H2O. Cis/Trans Selectivity in Transition Metal(II) Dihalide Tetrahydrate". Inorganica Chimica Acta. 192 (2): 173–181. doi:10.1016/S0020-1693(00)80756-2.
  3. ^ Winter, G. (1973). "Iron(II) Halides". Inorganic Syntheses. Inorganic Syntheses. Vol. 14. pp. 99–104. doi:10.1002/9780470132456.ch20. ISBN 9780470132456.
  4. ^ N. S. Gill, F.. B. Taylor Inorganic Syntheses 1967, volume 9, page 136-142. doi:10.1002/9780470132401.ch37
  5. ^ Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5
  6. ^ Wilkinson, M. K.; Cable, J. W.; Wollan, E. O.; Koehler, W. C. (15 January 1959). "Neutron Diffraction Investigations of the Magnetic Ordering in FeBr2, CoBr2, FeCl2, and CoCl2". Physical Review. 113 (2): 497–507. Bibcode:1959PhRv..113..497W. doi:10.1103/PhysRev.113.497.
  7. ^ Jacobs, I. S.; Lawrence, P. E. (10 December 1967). "Metamagnetic Phase Transitions and Hysteresis in FeCl2". Physical Review. 164 (2): 866–878. Bibcode:1967PhRv..164..866J. doi:10.1103/PhysRev.164.866.
  • v
  • t
  • e
Fe(-II)
  • H2Fe(CO)4
  • Na2Fe(CO)4
Fe(0)
  • Fe(CO)5
  • Fe2(CO)9
  • Fe3(CO)12
  • Fe(CO)3CH3COC2H2C6H6
Fe(I)
  • FeH
Organoiron(I) compounds
  • (C5H5FeCO)2(CO)2
    • Fe(0,II)
    • Fe3C
    Fe(II)
    • FeH2
    • Mg2FeH6
    • FeF2
    • FeCl2
    • Fe(ClO4)2
    • FeBr2
    • FeI2
    • FeO
    • Fe(OH)2
    • FeS
    • FeSO4
    • (NH4)2Fe(SO4)2·6H2O
    • FeSe
    • FeSeO4
    • Fe(NO3)2
    • Fe3(PO4)2
    • FeSi2
    • Fe(BF4)2
    • FeCr2O4
    • FeMoO4
    • FeTiO3
    • FeCO3
    • FeC2O4
    • Fe(C2H3O2)2
    • Fe(C3H5O3)2
    • FeC6H6O7
    • FeC12H22O14
    • FeI2(CO)4
    Organoiron(II) compounds
    • Fe(C5H5)2
    • Fe(C5H5)(CO)2I
    • Fe(C5H4P(C6H5)2)2
    • C4H4Fe(CO)3
    • C4H6Fe(CO)3
    Fe(0,III)Fe(II,III)
    • Fe3O4
    • Fe3S4
    Fe(III)
    • FeI3
    • FeBr3
    • FeCl3
    • FeF3
    • FeP
    • Fe(NO3)3
    • Fe(acac)3
    • FeOCl
    • [(C2H5)4N][O(FeCl3)2]
    • FeO(OH)
    • FePO4
    • Fe4(P2O7)3
    • Fe2(CrO4)3
    • Fe2(C2O4)3
    • Fe2O3
    • Fe2(SeO3)3
    • Fe2S3
    • Fe2(SO4)3
    • Fe(N3)3
    • NH4Fe(SO4)2·12H2O
    Organoiron(III) compounds
    • Fe(C5H5)2BF4
    • C6H8O7⋅xFe3+⋅yNH3
    • C
      54      H
      105      FeO
      6
    Fe(IV)
    • FeF4
    Fe(VI)
    • K2FeO4
    • BaFeO4
    Purported
    • v
    • t
    • e
    Br(−I)
    • Br−
    • CH3Br
    • CH2Br2
    • CHBr3
    • CBr4
    • HBr
    • C3H5Br
    Br(−I,I)
    • Br3−
    Br(I)
    • BrCl
    • BrF
    • BrN3
    • BrNO3
    • Br2O
    • BrO−
    • NBr3
    Br(II)
    Br(I,V)
    • Br2O3
    Br(III)
    • BrF3
    • BrO2−
    Br(IV)
    • BrO2
    Br(V)
    • BrF5
    • Br2O5
    • BrO3−
    • BrOF3
    • BrO2F
    Br(VII)
    • BrO4−
    • BrO3F